Cellulose nanofibers (CNF) as reinforcement for cementitious matrices: a systematic literature review
Abstract
The aim of this study is to conduct a systematic literature review of the last five years on the use of cellulose nanofibers (CNF) in cementitious composites. The main production and dispersion methods are presented, with emphasis on their effect on the behavior of cement-based materials. The study considered the influence of CNF on the fresh and hardened state properties: rheology, hydration, compressive strength, flexural strength, fracture energy, among others. CNF show positive effects on mechanical properties; however, further research is still necessary to optimize the production and pretreatment processes of CNF; establishing relationships regarding the durability of composites with CNF, and identifying possible environmental impacts of their use.
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References
Abdellaoui, H., Bouhfid, R. (2020), Review of nanocellulose and nanohydrogel matrices for the development of sustainable future materials. In Sustainable Nanocellulose and Nanohydrogels from Natural Sources, 155-176. https://doi.org/10.1016/B978-0-12-816789-2.00007-9 DOI: https://doi.org/10.1016/B978-0-12-816789-2.00007-9
Abdul Khalil, H. P. S., et al. (2012), Green composites from sustainable cellulose nanofibrils: A review. Carbohydrate Polymers. 87(2):963–979. https://doi.org/10.1016/j.carbpol.2011.08.078 DOI: https://doi.org/10.1016/j.carbpol.2011.08.078
Akhlaghi, M. A., et al. (2020), Application of bacterial nanocellulose fibers as reinforcement in cement composites. Construction and Building Materials. 241:118061. https://doi.org/10.1016/j.conbuildmat.2020.118061 DOI: https://doi.org/10.1016/j.conbuildmat.2020.118061
Alzoubi, H. H., et al. (2020), Performance of cementitious composites with nano PCMs and cellulose nanofibers. Construction and Building Materials. 236:117483. https://doi.org/10.1016/j.conbuildmat.2019.117483 DOI: https://doi.org/10.1016/j.conbuildmat.2019.117483
Bakkari, M., et al. (2019), Preparation of cellulose nanofibers by TEMPO-oxidation of bleached chemi-thermomechanical pulp for cement applications. Carbohydrate Polymers. 203:238–245. https://doi.org/10.1016/j.carbpol.2018.09.036 DOI: https://doi.org/10.1016/j.carbpol.2018.09.036
Barnat-Hunek, D., et al. (2019), Effect of cellulose nanofibrils and nanocrystals on physical properties of concrete. Construction and Building Materials. 223:1–11. https://doi.org/10.1016/j.conbuildmat.2019.06.145 DOI: https://doi.org/10.1016/j.conbuildmat.2019.06.145
BarrÃa, J. C., et al. (2021), Effect of bacterial nanocellulose on the fresh and hardened states of oil well cement. Journal of Petroleum Science and Engineering. 199. https://doi.org/10.1016/j.petrol.2020.108259 DOI: https://doi.org/10.1016/j.petrol.2020.108259
Cao, Z., et al. (2020), The sponge effect and carbon emission mitigation potentials of the global cement cycle. Nature communications. 11(1): 1-9. https://doi.org/10.1038/s41467-020-17583-w DOI: https://doi.org/10.1038/s41467-020-17583-w
Cengiz, A., et al (2017), Flexural stress enhancement of concrete by incorporation of algal cellulose nanofibers. Construction and Building Materials. 149:289–295. https://doi.org/10.1016/j.conbuildmat.2017.05.104 DOI: https://doi.org/10.1016/j.conbuildmat.2017.05.104
Claramunt, J., et al. (2019), Effect of nanocelluloses on the microstructure and mechanical performance of CAC cementitious matrices. Cement and Concrete Research. 119:64–76, 2019. DisponÃvel em: https://doi.org/10.1016/j.cemconres.2019.02.006 DOI: https://doi.org/10.1016/j.cemconres.2019.02.006
Correia, V. C., et al., (2018), Nanofibrillated cellulose and cellulosic pulp for reinforcement of the extruded cement based materials. Construction and Building Materials. 160:376–384. https://doi.org/10.1016/j.conbuildmat.2017.11.066 DOI: https://doi.org/10.1016/j.conbuildmat.2017.11.066
Dhali, K., et al. (2021), A review of nanocellulose as a new material towards environmental sustainability. Science of the Total Environment. 775:145871. https://doi.org/10.1016/j.scitotenv.2021.145871 DOI: https://doi.org/10.1016/j.scitotenv.2021.145871
Dongre, M., Suryawanshi, V. B. (2021), Analysis of cellulose based nanocomposites & potential applications. Materials Today: Proceedings. 45:3476–3482. https://doi.org/10.1016/j.matpr.2020.12.943 DOI: https://doi.org/10.1016/j.matpr.2020.12.943
UN Environment, et al., (2018), Eco-efficient cements: Potential economically viable solutions for a low-CO2 cement-based materials industry. Cement and Concrete Research. 114:2-26. https://doi.org/10.1016/j.cemconres.2018.03.015 DOI: https://doi.org/10.1016/j.cemconres.2018.03.015
Ez-zaki, H., et al. (2021), Correction to: Influence of cellulose nanofibrils on the rheology, microstructure and strength of alkali activated ground granulated blast-furnace slag: a comparison with ordinary Portland cement. Materials and Structures/Materiaux et Constructions. 54(2). https://doi.org/10.1617/s11527-021-01665-2 DOI: https://doi.org/10.1617/s11527-021-01665-2
Fonseca, C. S., et al. (2019), Jute fibers and micro/nanofibrils as reinforcement in extruded fiber-cement composites. Construction and Building Materials. 211:517–527. https://doi.org/10.1016/j.conbuildmat.2019.03.236 DOI: https://doi.org/10.1016/j.conbuildmat.2019.03.236
Goncalves, J., et al. (2019), Cellulose nanofibres (CNF) for sulphate resistance in cement based systems. Cement and Concrete Composites. 99:100–111. https://doi.org/10.1016/j.cemconcomp.2019.03.005 DOI: https://doi.org/10.1016/j.cemconcomp.2019.03.005
Goncalves, J., et al. (2021), Turbidity-based measurement of bleeding in fresh cement paste as affected by cellulose nanofibres. Cement and Concrete Composites. 123:104197. https://doi.org/10.1016/j.cemconcomp.2021.104197 DOI: https://doi.org/10.1016/j.cemconcomp.2021.104197
Goncalves, J., et al. (2020), Cellulose nanofibres mitigate chloride ion ingress in cement-based systems. Cement and Concrete Composites. 114. https://doi.org/10.1016/j.cemconcomp.2020.103780 DOI: https://doi.org/10.1016/j.cemconcomp.2020.103780
Guo, A., et al. (2020), A Review on the Application of Nanocellulose in Cementitious Materials. Nanomaterials. 10(12):2476. https://doi.org/10.3390/nano10122476 DOI: https://doi.org/10.3390/nano10122476
Hassan, S. H., et al. (2021), TEMPO-oxidized nanocellulose films derived from coconut residues: Physicochemical, mechanical and electrical properties. International Journal of Biological Macromolecules. 180:392–402. https://doi.org/10.1016/j.ijbiomac.2021.03.066 DOI: https://doi.org/10.1016/j.ijbiomac.2021.03.066
Hisseine, O. A., et al. (2018a) Feasibility of using cellulose filaments as a viscosity modifying agent in self-consolidating concrete. Cement and Concrete Composites, 94:327–340. https://doi.org/10.1016/j.cemconcomp.2018.09.009 DOI: https://doi.org/10.1016/j.cemconcomp.2018.09.009
Hisseine, O. A., et al. (2018b), Influence of cellulose filaments on cement paste and concrete. Journal of materials in civil engineering. 30(6):04018109. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002287 DOI: https://doi.org/10.1061/(ASCE)MT.1943-5533.0002287
Hisseine, O. A., et al. (2019), Nanocellulose for improved concrete performance: A macro-to-micro investigation for disclosing the effects of cellulose filaments on strength of cement systems. Construction and Building Materials. 206:84–96. https://doi.org/10.1016/j.conbuildmat.2019.02.042 DOI: https://doi.org/10.1016/j.conbuildmat.2019.02.042
Hoyos, C. G., et al. (2019), Cellulose nanofibrils extracted from fique fibers as bio-based cement additive. Journal of Cleaner Production. 235:1540–1548. https://doi.org/10.1016/j.jclepro.2019.06.292 DOI: https://doi.org/10.1016/j.jclepro.2019.06.292
Jiao, L., et al. (2016), Natural Cellulose Nanofibers As Sustainable Enhancers in Construction Cement. PLoS ONE. 11(12):e0168422. https://doi.org/10.1371/journal.pone.0168422 DOI: https://doi.org/10.1371/journal.pone.0168422
Kamasamudram, K. S., et al. (2021), Cellulose Nanocomposites for Performance Enhancement of Ordinary Portland Cement-Based Materials. Transportation Research Record. https://doi.org/10.1177/0361198120958421 DOI: https://doi.org/10.1177/0361198120958421
Kamasamudram, K. S., et al. (2021a), Effects of ligno– and delignified– cellulose nanofibrils on the performance of cement-based materials. Journal of Materials Research and Technology. 13: 321–335. https://doi.org/10.1016/j.jmrt.2021.04.090 DOI: https://doi.org/10.1016/j.jmrt.2021.04.090
Kamasamudram, K. S., et al. (2021b), Cellulose nanofibrils with and without nanosilica for the performance enhancement of Portland cement systems. Construction and Building Materials. 285:121547. https://doi.org/10.1016/j.conbuildmat.2020.121547 DOI: https://doi.org/10.1016/j.conbuildmat.2020.121547
Klemm, D., et al. (2011), Nanocelluloses: a new family of natureâ€based materials. Angewandte Chemie International Edition. 50(24):5438-5466. https://doi.org/10.1002/anie.201001273 DOI: https://doi.org/10.1002/anie.201001273
Kolour, H., et al. (2020), Hydration and early age properties of cement pastes modified with cellulose nanofibrils. Transportation Research Record. 0361198120945993. https://doi.org/10.1177/0361198120945993 DOI: https://doi.org/10.1177/0361198120945993
Lootens, D., Bentz, D. P. (2016), On the relation of setting and early-age strength development to porosity and hydration in cement-based materials. Cement and Concrete Composites. 68:9-14. https://doi.org/10.1016/j.cemconcomp.2016.02.010 DOI: https://doi.org/10.1016/j.cemconcomp.2016.02.010
Mejdoub, R., et al. (2016), Nanofibrillated cellulose as nanoreinforcement in Portland cement: Thermal, mechanical and microstructural properties. Journal of Composite Materials. 51(17):2491-2503. https://doi.org/10.1177/0021998316672090 DOI: https://doi.org/10.1177/0021998316672090
Nassiri, S., et al. (2021), Comparison of unique effects of two contrasting types of cellulose nanomaterials on setting time, rheology, and compressive strength of cement paste. Cement and Concrete Composites. 123:104201. https://doi.org/10.1016/j.cemconcomp.2021.104201 DOI: https://doi.org/10.1016/j.cemconcomp.2021.104201
Nishimura, T., et al. (2019), Effects of powdery cellulose nanofiber addition on the properties of glass ionomer cement. Materials. 12(19):3077. https://doi.org/10.3390/ma12193077 DOI: https://doi.org/10.3390/ma12193077
Ogura, I., et al. (2020), Measurements of cellulose nanofiber emissions and potential exposures at a production facility. NanoImpact. 20:100273. https://doi.org/10.1016/j.impact.2020.100273 DOI: https://doi.org/10.1016/j.impact.2020.100273
Panesar, D., et al. (2017), The effect of sodium hydroxide surface treatment on the tensile strength and elastic modulus of cellulose nanofiber. Sustainable and Nonconventional Construction Materials using Inorganic Bonded Fiber Composites. 17–26. https://doi.org/10.1016/B978-0-08-102001-2.00002-4 DOI: https://doi.org/10.1016/B978-0-08-102001-2.00002-4
Santos, R. F., et al. (2021), Nanofibrillated cellulose and its applications in cement-based composites: A review. Construction and Building Materials. 288:123122. https://doi.org/10.1016/j.conbuildmat.2021.123122 DOI: https://doi.org/10.1016/j.conbuildmat.2021.123122
Sedan, D., et al. (2008), Mechanical properties of hemp fibre reinforced cement: Influence of the fibre/matrix interaction. Journal of the European Ceramic Society. 28(1):183-192. https://doi.org/10.1016/j.jeurceramsoc.2007.05.019 DOI: https://doi.org/10.1016/j.jeurceramsoc.2007.05.019
Sun, X., et al. (2017), Rheology, curing temperature and mechanical performance of oil well cement: Combined effect of cellulose nanofibers and graphene nano-platelets. Materials & Design. 114:92-101. https://doi.org/10.1016/j.matdes.2016.10.050 DOI: https://doi.org/10.1016/j.matdes.2016.10.050
Sun, X., et al. (2016), Cellulose nanofibers as a modifier for rheology, curing and mechanical performance of oil well cement. Scientific reports. 6(1):1-9. https://doi.org/10.1038/srep31654 DOI: https://doi.org/10.1038/srep31654
Tang, Z., et al. (2019), Influence of cellulose nanoparticles on rheological behavior of oil well cement-water slurries. Materials. 12(2):291. https://doi.org/10.3390/ma12020291 DOI: https://doi.org/10.3390/ma12020291
Zhang, S., et al. (2021), High-flexural-strength of geopolymer composites with self-assembled nanofiber networks. Ceramics International. 47(22):31389–31398. https://doi.org/10.1016/j.ceramint.2021.08.014 DOI: https://doi.org/10.1016/j.ceramint.2021.08.014
Zhang, Z., Scherer, G. W. (2020), Measuring chemical shrinkage of ordinary Portland cement pastes with high water-to-cement ratios by adding cellulose nanofibrils. Cement and Concrete Composites. 111:103625. https://doi.org/10.1016/j.cemconcomp.2020.103625 DOI: https://doi.org/10.1016/j.cemconcomp.2020.103625
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