Behavior of mortars with different types of cement when induced to Delayed Ettringite Formation (DEF)

  • Friancieli Tiecher Escola Politécnica, Mestrado em Engenharia Civil, IMED, Passo Fundo, Brazil
  • Marinês Langoski Engenharia Civil, IMED, Passo Fundo, Brazil
  • Nicole Hasparyk Departamento de Durabilidade, Eletrobrás Furnas S.A., Aparecida de Goiânia, Brazil
Keywords: ettringite, DEF, expansions, mechanical properties, mortar, microstructure

Abstract

The purpose of this paper is to present an evaluation of different types of cement and the incidence of Delayed Ettringite Formation (DEF) through mortar composites cast in the laboratory and exposed to a high curing temperature over a 12-month study period. DEF represents one of the types of Internal Sulfate Attacks (ISA) related to an expansive chemical reaction that occurs inside of concrete involving the sulfates from cement. Experiments involved the assessment of expansions, compressive and tensile strengths as well as microstructural characteristics over time. It was observed that tests performed on mortars and with a specific mix required an extended evaluation period to distinguish the behaviors. Furthermore, high early-strength cement featured the worst binder when faced with DEF.

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Author Biographies

Friancieli Tiecher, Escola Politécnica, Mestrado em Engenharia Civil, IMED, Passo Fundo, Brazil

Francieli Tiecher is a Professor and Coordinator of the Master's Program in Civil Engineering at IMED. She received her Ph.D. in civil engineering. Her research interests include durability of concrete structures, with an emphasis on alkali-silica reaction and sulfate attack.

Marinês Langoski, Engenharia Civil, IMED, Passo Fundo, Brazil

Marinês Langoski is a Researcher at the Department of Civil Engineering Research at IMED, Passo Fundo, Brazil. Her research interests include the durability of structures.

Nicole Hasparyk, Departamento de Durabilidade, Eletrobrás Furnas S.A., Aparecida de Goiânia, Brazil

Nicole Pagan Hasparyk works at ELETROBRAS Furnas with concrete structures from energy generation projects. She received her PhD from the Federal University of Rio Grande do Sul, Porto Alegre, Brazil. She received the ACI Wason Medal for Materials Research in 2003. Her research interests include concrete technology, microstructure, durability, particularly in expansive reactions such as alkali-aggregate reaction and sulphate attack, and sustainability issues.

References

Adamopoulou, E., Pipilikaki, P., Katsiotis, M. S, Chaniotakis, M., Katsioti, M. (2011). “How sulfates and increased temperature affect delayed ettringite formation (DEF) in white cement mortars.†Construction and Building Materials, Vol. 25, pp. 3583-3590. https://doi.org/10.1016/j.conbuildmat.2011.03.051 DOI: https://doi.org/10.1016/j.conbuildmat.2011.03.051

Al Shamaa, M., Lavaud, S., Divet, L., Colliat, J.B, Nahas, G., Torrenti, J. M. (2016). “Influence of limestone filler and of the size of the aggregates on DEF.†Cement Concrete Composites, Vol. 71, pp. 175-180. https://doi.org/10.1016/j.cemconcomp.2016.05.007 DOI: https://doi.org/10.1016/j.cemconcomp.2016.05.007

Amine, Y., Leklou, N., Amiri, O. (2017). “Effect of supplementary cementitious materials (SCM) on delayed ettringite formation in heat cured concretes.†Energy Procedia, Vol. 139, pp. 565-570. https://doi.org/10.1016/j.egypro.2017.11.254 DOI: https://doi.org/10.1016/j.egypro.2017.11.254

Asamoto, S., Murano, K., Kurashige, I., Nanayakkara, A. (2017). “Effect of carbonate ions on delayed ettringite formation.†Construction and Building Materials, Vol. 147, pp. 221-226. https://doi.org/10.1016/j.conbuildmat.2017.04.107 DOI: https://doi.org/10.1016/j.conbuildmat.2017.04.107

Bronholo, J. L. (2020). Estudo do ataque individual e misto de DEF e RAA e de seus efeitos deletérios nas propriedades físico-químicas e mecânicas de concretos e argamassas de cimento Portland pozolânico e de alta resistência. Dissertação de Mestrado em Engenharia Civil – LACTEC, Curitiba, Brasil.

Collepardi, M. A. (2003). “State-of-the-art review on delayed ettringite attack on concrete.†Cement and Concrete Composites, Vol. 25, pp. 401-407. https://doi.org/10.1016/S0958-9465(02)00080-X DOI: https://doi.org/10.1016/S0958-9465(02)00080-X

Divet, L., Randriambololona, R. (1998). “Delayed ettringite formation: the effect of temperature and basicity on the interaction of sulphate and C-S-H phase.†Cement and Concrete Research, Vol. 28, pp. 357-363. https://doi.org/10.1016/S0008-8846(98)00006-4 DOI: https://doi.org/10.1016/S0008-8846(98)00006-4

Dayarathne, W. (2013). “Evaluation of the potential for delayed ettringite formation in concrete.†National Engineering Conference, Sri Lanka.

Fu, Y., Ding, J., Beaudoin, J. J. (1997). “Expansion of Portland cement mortar due to internal sulfate attack.†Cement and Concrete Research, Vol. 27, pp. 1299-1306. https://doi.org/10.1016/S0008-8846(97)00133-6 DOI: https://doi.org/10.1016/S0008-8846(97)00133-6

Godart, B. (2017). “Pathology, Assessment and Treatment Structures Affected by Delayed Ettringite Formation.†Structural Engineering International, Vol. 27, pp. 362-369. https://doi.org/10.2749/101686617X14881932436771 DOI: https://doi.org/10.2749/101686617X14881932436771

Hasparyk, N. P, Kuperman, S. C., Torres, J. R. (2016). “Combined attack from ARS and DEF in the foundation.†In: Proceeding of 15º International Conference on Alkali Aggregate Reaction in Concrete – 15th ICAAR, Ed. Bernardes, H.; Hasparyk, N.P. São Paulo, 2016.

Ifsttar (2018). “Recommendations for preventing disorders due to Delayed Ettringite Formationâ€. Merne-la-Vallée. Technics and methods, GTI5-A, 70 pp ISBN 978-2-85782-745-0.

Leklou, N., Aubert, J. E., Escadeillas, G. (2013). “Influence of various parameters on heat induced internal sulfate attack.†European Journal of Environmental and Civil Engineering, Vo. 17, pp. 141-153. https://doi.org/10.1080/19648189.2012.755338 DOI: https://doi.org/10.1080/19648189.2012.755338

Leklou, N., Nguyen, V-H., Mounanga, P. (2017) “The effect of the Partial Cement Substitution with Fly Ash on Delayed Ettringite Formation in Heat-cured Mortarsâ€. Journal of Civil Engineering, Vol. 21, pp. 1359-1366. https://doi.org/10.1007/s12205-016-0778-9 DOI: https://doi.org/10.1007/s12205-016-0778-9

Martin, R.-P., Sanchez, L., Founier, B., Toutlemonde, F. (2016). “Diagnosis of AAR and DEF: Comparison of residual expansion, stiffness test and damage rating indexâ€. International Conference on Alkali Aggregate Reaction in Concrete - ICAAR.

Melo, et al. (2011) “Influência do calor de hidratação na formação da etringita tardia (DEF) em concreto com cimento Portland pozolânicoâ€. 53º Congresso Brasileiro do Concreto – IBRACON, Brasil.

Pavoine, A., Brunetaud, X., Divet, L. (2012). “The impact of cement parameters on Delayed Ettringite Formation.†Cement and Concrete Composites, Vol. 34, pp. 521-528. https://doi.org/10.1016/j.cemconcomp.2011.11.012 DOI: https://doi.org/10.1016/j.cemconcomp.2011.11.012

Ramlochan, T., Zacarias, P., Thomas, M. D. A., Hooton, R. D. (2003) “The effect of pozzolans and slag on the expansion of mortars cured at elevated temperature Part I: Expansive Behaviorâ€. Cement and Concrete Research, Vol. 33, 807-814. https://doi.org/10.1016/j.conbuildmat.2013.07.016 DOI: https://doi.org/10.1016/S0008-8846(02)01066-9

Rashidi, M., Paul, A., Kim, J. Y, Jacobs, L. J., Kurtis, K. E. (2017) “Insights into delayed ettringite formation damage through acoustic nonlinearity.†Cement and Concrete Research, Vol. 95, pp. 1-8. https://doi.org/10.1016/j.cemconres.2017.02.004 DOI: https://doi.org/10.1016/j.cemconres.2017.02.004

Schovanz, D. (2019). “Estudo da formação da etringita tardia (DEF) em concretos com cimento Portland pozolânico e de alta resistênciaâ€. Dissertação de Mestrado em engenharia civil – Faculdade IMED, Passo Fundo, Brasil.

Schovanz, D., Tiecher, F., Hasparyk, N. P., Kuperman, S., Lermen, R. T. (2021). Evaluation of Delayed Ettringite Formation through Physical, Mechanical, and Microstructural Assays. ACI Materials Journal, Vol. 119, pp. 101-109. https://doi.org/10.14359/51728282 DOI: https://doi.org/10.14359/51728282

Taylor, H. F., Famy, C., Scrivener, K. L. (2001). “Delayed ettringite formation.†Cement Concrete Composites, Vol. 31, pp. 683-693. https://doi.org/10.1016/S0008-8846(01)00466-5 DOI: https://doi.org/10.1016/S0008-8846(01)00466-5

Termkhajornkit, P., Nawa, T., Yamashiro, Y., Saito, T. “Self-healing ability of fly ash–cement systemsâ€. Cement and Concrete Research, Vol. 31, pp. 195-203. https://doi.org/10.1016/j.cemconcomp.2008.12.009 DOI: https://doi.org/10.1016/j.cemconcomp.2008.12.009

Van Tittelboom, K., De Belie, N. (2013). “Self-healing in cementitious materials – A review.†Materials, Vol. 6, nº 6, pp. 2182-2217. https://doi.org/10.3390/ma6062182 DOI: https://doi.org/10.3390/ma6062182

Published
2021-09-01
How to Cite
Tiecher, F., Langoski, M., & Hasparyk, N. (2021). Behavior of mortars with different types of cement when induced to Delayed Ettringite Formation (DEF). Revista ALCONPAT, 11(3), 1 - 16. https://doi.org/10.21041/ra.v11i3.537