Physical and chemical effects of limestone filler on the hydration of steam cured cement paste and mortar
The aim of the paper is to decouple the physical and chemical effects of limestone filler (LF), when used as a cement replacement. The effects were decoupled using LF and a chemically inert material (brucite Mg(OH)2). Paste, and mortar specimens were steam cured for 16 hours at 55°C. The heat of hydration, thermal analysis, x-ray diffraction, and compressive strength, were evaluated at 16 hours and at 28 days. LF can adversely affect the properties through dilution effect. However, heterogeneous nucleation compensates for the dilution effect at 16 hours while the production of mono-carboaluminate compensates for the dilution effect at 16 hours and 28 days. The study could be broadened by considering a wider temperature range. The originality lies in the method of decoupling the physical and chemical effects. Measurable effects of the physical and chemical contribution of LF are evident on the mechanical and transport material properties.
ASTM International (2010). “ASTM C1202: Standard test method for electrical indication of concrete's ability to resist chloride ion penetration.”, West Conshohocken, PA, USA.
ASTM International (2012). “ASTM C109: Standard test method for compressive strength of hydraulic cement mortars (Using 2-in. or [50-mm] Cube Specimens).”, West Conshohocken, PA, USA.
ASTM International (2013). “ASTM C1585: Standard test method for measurement of rate of absorption of water by hydraulic-cement concretes.”, West Conshohocken, PA, USA.
ASTM International (2009). “ASTM C1702: Standard test method for measurement of heat of hydration of hydraulic cementitious materials using isothermal conduction calorimetry.”, West Conshohocken, PA, USA.
Benhelal, E., Zahedi, G., Shamsaei, E., Bahadori A., (2013). “Global strategies and potentials to curb CO2 emissions in cement industry.” Journal of Cleaner Production, 51, 142–161. https://doi.org/10.1016/j.jclepro.2012.10.049
Bentz, D. (2006), “Modeling the influence of limestone filler on cement hydration using CEMHYD3D.” Cement and Concrete Composites, 28 (2), 124–129. https://doi.org/10.1016/j.cemconcomp.2005.10.006
Bentz, D., Irassar, E., Bucher, B., Weiss, W., (2009). “Limestone fillers conserve cement: part 1: an analysis based on power’s model.” Concrete International, 31 (11), 41–46.
Brunetaud, X., Linder, R., Divet, L., Duragrin, D., Damidot, D. (2006). “Effect of curing conditions and concrete mix design on the expansion generated by delayed ettringite formation.” Materials and Structures,40 (6), 567–578. https://doi.org/10.1617/s11527-006-9163-3
BIBM (2014), European Precast Concrete Factbook, 1–12. URL: https://bibm.eu/wp-content/uploads/2019/07/BIBM-Factbook-2014.pdf
Celik, K., Meral, C., Petek Gursel, A., Mehta, P. K., Horvath, A., Monteiro, P. J. M. (2015). “Mechanical properties, durability, and life-cycle assessment of self-consolidating concrete mixtures made with blended Portland cements containing fly ash and limestone powder.” Cement and Concrete Composites, 56, 59–72. https://doi.org/10.1016/j.cemconcomp.2014.11.003
Chowaniec, O., (2012). “Limestone addition in cement.” Doctoral Thesis, École Polytechnique Fédérale de Lausanne, Lausanne, Switzerland.
Canadian Standards Association (CSA) (2009). “A23.1/A23.2: Concrete materials and methods of concrete construction/test methods and standard practices for concrete.”, Ottawa, Canada.
Canadian Standards Association (CSA) (2014). “A23.1/A23.2: Concrete materials and methods of concrete construction/test methods and standard practices for concrete.”, Ottawa, Canada.
Esmaeilkhanian, B., Khayat, K. H., Yahia, A., Feys, D. (2014). “Effects of mix design parameters and rheological properties on dynamic stability of self-consolidating concrete.” Cement and Concrete Composites, 54, 21-28, https://doi.org/10.1016/j.cemconcomp.2014.03.001
Ezziane, K., Kadri, E., Hallal, A., Duval, R. (2010). “Effect of mineral additives on the setting of blended cement by the maturity method.” Materials and Structures, 43(3), 393–401. https://doi.org/10.1617/s11527-009-9498-7
Gao, F. (2012). “Advances in polymer nanocomposites, types and applications”. 1st ed. Woodhead Publishing, England.
Hawkins, P., Tennis, P., Detwiler, R., (2003). “The use of limestone in Portland cement: a state-of-the-art review.” EB227, The Portland Cement Association (PCA), 5–36. ISBN: 0-89312-229-7.
Hooton, D., Nokken, M., Thomas, M., (2007). “Portland-limestone cement: state-of-the-art report and gap analysis for CSA A 3000.” SN3053, Cement Association of Canada, 1–59.
Irassar, E. (2009). “Sulfate attack on cementitious materials containing limestone filler - a review.” Cement and Concrete Research, 39 (3), 241–254. https://doi.org/10.1016/j.cemconres.2008.11.007
Kakali, G., Tsivilis, S., Aggeli, E., and Bati, M., (2000). “Hydration products of C3A, C3S and Portland cement in the presence of CaCO3.” Cement and Concrete Research, 30 (7), 2–6. https://doi.org/10.1016/S0008-8846(00)00292-1
Kenai, S., Soboyejo, W., Soboyejo, A. (2004). “Some engineering properties of limestone concrete.” Materials and Manufacturing Processes, 19 (5), 949–961. https://doi.org/10.1081/AMP-200030668
Kumar, A., Oey, T., Falla, G. P., Henkensiefken, R., Neithalath, N., Sant, G. (2013). “A comparison of intergrinding and blending limestone on reaction and strength evolution in cementitious materials.” Construction and Building Materials, 43, 428–435. https://doi.org/10.1016/j.conbuildmat.2013.02.032
Kuzel, H., Baier, H. (1996). “Hydration of calcium aluminate cements in the presence of calcium carbonate.” European Journal of Mineralogy, 8(1), 129–141. https://doi.org/10.1127/ejm/8/1/0129
Lin, F., Meyer, C. (2009). “Hydration kinetics modeling of Portland cement considering the effects of curing temperature and applied pressure.” Cement and Concrete Research, 39 (4), 255–265. https://doi.org/10.1016/j.cemconres.2009.01.014
Maria, F. (2011). “Handbook of thermogravimetric system of minerals and its use in geological practice.” Geological Institute of Hungary, Budapest, 13–55. ISBN 978-963-671-288-4.
Mohammadi, J., South, W. (2016). “Effects of intergrinding 12% limestone with cement on properties of cement and mortar.” Journal of Advanced Concrete Technology, 14 (5), 215–228. https://doi.org/10.3151/jact.14.215
Moir, G., Kelham, S. (1993). “Performance of limestone-filled cements.” Building Research Establishment report. Her Maj.'s Stat. Off. London, Watford, 245, ISBN: 0851255671
Moore, J., Stanitski, C., Jurs, P. (2009). “Principles of chemistry: the molecular science.” 1st ed., Brooks Cole, USA, 143–148. ISBN0495390798.
Péra, J., Husson, S., Guilhot, B. (1999). “Influence of finely ground limestone on cement hydration.” Cement and Concrete Composites, 21 (2), 99–105. https://doi.org/10.1016/S0958-9465(98)00020-1
Ramezanianpour, A. M., Hooton, R. D. (2013). “Sulfate resistance of Portland-limestone cements in combination with supplementary cementitious materials.” Materials and Structures, 46 (7),1061–1073. https://doi.org/10.1617/s11527-012-9953-8
Santhanam, M. (2013). “Performance of cement-based materials in aggressive aqueous environments.” RILEM State-of-the-Art Reports, 10, 75–90.
Schmidt, M. (1992). “Cement with interground additives– capabilities and environmental relief, part 1.” Zement- Kalk-Gips, 45 (2), 64–69.
Sellevold, E., Bager, D., Klitgaard-Jensen, E., Knudsen, T. (1982). “Silica fume-cement pastes: hydration and pore structure.” Condensed Silica Fume in Concrete, Institutt for Bygningsmateriallære, Norges Tekniske Høgskole, Norway, BML 82.610, 19–50.
Sirisawat, I., Baingam, L., Saengsoy, W., Krammart, P., and Tangtermsirikul, S. (2014). “Sodium and magnesium sulfate resistance of mortars with interground limestone and limestone powder replacing cements”. Journal of Advanced Concrete Technology, 12 (10), 403-412. https://doi.org/10.3151/jact.12.403
Tennis, P. D., Thomas, M. D. A., Weiss, W. J. (2011), State-of-the-Art Report on Use of Limestone in Cements at Levels of up to 15%, SN3148, Portland Cement Association, Skokie, Illinois, USA, 78 pages.
Tikkanen, J., Cwirzen, A., and Penttala, V. (2011). “Mineral powder concrete – effects of powder content on concrete properties.” Magazine of Concrete Research, 63 (12), 893–903. https://doi.org/10.1680/macr.10.00048
Tsivilis, S., Tsantilas, J., Kakali, G., Chaniotakis, E., and Sakellariou, A. (2003). “The permeability of Portland limestone cement concrete.” Cement and Concrete Research, 33 (9), 1465–1471. https://doi.org/10.1016/S0008-8846(03)00092-9
Geological Survey, U. S. (2014). Mineral commodity summaries; February. https://doi.org/10.3133/70100414
Wang, J. (2010). “Hydration mechanism of cements based on low-CO2 clinkers containing belite, ye’elimite and calcium alumino-ferrite.” PhD Thesis, University of Lille, France.
Yang, C. C., Chiang, C. T. (2005). “On the relationship between pore structure and charge passed from RCPT in mineral-free cement-based materials.” Materials Chemistry and Physics, 93 (1), 202–207. https://doi.org/10.1016/j.matchemphys.2005.03.044
Ye, G., Liu, X., De Schutter, G., Poppe, M., Taerwe, L. (2007). “Influence of limestone powder used as filler in SCC on hydration and microstructure of cement pastes.” Cement and Concrete Composites, 29 (2), 94–102. https://doi.org/10.1016/j.cemconcomp.2006.09.003
Zhang, T., Vandeperre, L. J., Cheeseman, C. R (2014). “Formation of magnesium silicate hydrate (M-S-H) cement pastes using sodium hexametaphosphate.” Cement and Concrete Research, 65, 8–14. https://doi.org/10.1016/j.cemconres.2014.07.001
Zhange, P., Li, S. X., and Zhange, Z. F. (2011). “General relationship between strength and hardness.” Materials Science and Engineering: A, 529, 62–73. https://doi.org/10.1016/j.msea.2011.08.061
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